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Measure the mechanical properties of polymers

Explore the different ways in which a Texture Analyser can measure the physical and mechanical characteristics of polymers.

Why measure the mechanical properties of polymers? How a Texture Analyser can be applied to polymer mechanical property measurement? Typical measurements Typical graphs indicating relevant mechanical property parameters Typical product test and graph Case studies Probes and attachments for measuring the mechanical properties of polymers Test methods Using the Texture Analyser for new polymer material and product ideas Recent research
Coloured polymer pellets

Why measure the mechanical properties of polymers?

The measurement of mechanical properties in polymers is fundamental given the ubiquitous presence of polymers in modern society.

These versatile materials manifest in various forms, such as films, foams, adhesives, coatings, rubbers, composites, textiles, and fibres, serving both functional and cosmetic purposes. Whether natural polymers found in foods, wood, or paper, or synthetic polymers employed as engineering materials, meticulous testing is essential to ensure fitness for purpose.

Polymer research, development, and quality control heavily rely on mechanical property measurements to optimise material selection, design components capable of withstanding application-specific forces, assess part strength and longevity under varying stress conditions, and implement effective quality control checks.

The diversity of polymer properties and applications necessitates a broad spectrum of testing approaches beyond traditional tensile and bend tests, including flexural, compressive, and tensile tests, often in combination to simulate real-world stress states. Imitative measurements allow for more realistic testing scenarios, unconstrained by standard methods, offering testing flexibility and meaningful results.

Time-dependent creep and relaxation properties are of particular interest due to the viscoelastic nature of most polymers, assessed through similar configurations as standard tests but involving hold periods at set stress or strain levels, or cycles at various test speeds.

In essence, the measurement of mechanical properties in polymers underpins their suitability for diverse applications and ensures their performance and quality meet the stringent demands of the modern world.

Researcher holding a sample of a new material
Person crushing a single-use plastic bottle with their hands
People stretching film over a cardboard box
Researcher holding a sample of a new material
Person crushing a single-use plastic bottle with their hands
People stretching film over a cardboard box

How a Texture Analyser can be applied to polymer mechanical property measurement?

Polymers, given their extensive use across industries, require a deep understanding of their mechanical properties to ensure they meet specific performance criteria. The use of a Texture Analyser in this context is instrumental. Here's how it benefits the manufacture and development of polymers:

  • Comprehensive property evaluation: Texture Analysers can evaluate a wide range of mechanical properties, such as tensile strength, elongation, compression modulus, and flexural strength, offering a holistic view of a polymer's mechanical behaviour.
  • Quality assurance and control: Regular testing ensures that produced polymers consistently meet desired specifications, essential for maintaining brand reputation and reducing wastage.
  • Optimising formulations: When modifying polymer formulations with additives, fillers, or plasticisers, mechanical testing helps understand their effect on the final product, leading to optimised formulations.
  • Predictive modelling and lifetime assessment: By studying how polymers age and degrade over time under various conditions, manufacturers can predict product longevity and performance.
  • Regulatory compliance: For polymers used in specific sectors, like medical or food packaging, compliance with set mechanical standards is mandatory. Regular testing ensures adherence to these benchmarks.
  • Innovation and novel material development: For researchers developing new polymers or biopolymers, mechanical testing provides critical data to evaluate and compare the potential of these innovative materials.
  • Processing parameter optimisation: Mechanical properties of polymers can vary based on processing conditions like temperature, pressure, and shear. Testing allows manufacturers to refine these parameters for desired properties.
  • End-use suitability assessment: Different applications demand distinct mechanical properties. For example, a polymer used in a flexible water bottle varies from that in a rigid car bumper. Testing ensures polymers are fit for their intended application.
  • Economic efficiency: By understanding the exact mechanical properties required for a specific application, manufacturers can avoid over- or under-engineering polymer products, leading to cost savings.
  • Environmental and sustainability evaluations: As the push for recyclable and biodegradable polymers grows, understanding their mechanical properties is crucial to ensure they're viable alternatives to traditional polymers.
  • Stress-strain analysis: This aids in understanding the elastic or plastic behaviour of polymers, which can inform design decisions, especially in load-bearing applications.
  • Feedback mechanism: Regular testing can serve as feedback for raw material suppliers, ensuring the quality of monomers, additives, and other components.
  • Validation of material claims: For polymers marketed with specific claims, such as "high impact resistance" or "superior flexibility", empirical data from a Texture Analyser offers validation.

Incorporating a Texture Analyser in the polymer development and manufacturing process facilitates a data-driven approach. This not only ensures quality and performance but also spurs innovation, aligns with regulatory requirements, and caters to evolving industry demands, all while ensuring efficiency and cost-effectiveness.

Typical measurements

Polymers, both thermoplastics and thermosetting, have diverse applications due to their versatile mechanical properties. Texture analysers are vital tools for measuring and characterizing these properties.

Here are the mechanical properties that can be assessed for polymers using a Texture Analyser:

Hardness

The resistance of a polymer's surface to indentation or penetration.

Compressive strength

Determines the ability of the polymer to withstand compressive forces without deforming or breaking.

Elongation

This measures the percentage increase in length of a polymer sample when it is stretched until it breaks.

Flexural strength

Measures the force required to bend a polymer sample to a specific degree without fracturing.

Tear resistance

Determines the force required to initiate or propagate a tear in a polymer, which is especially crucial for thin films or sheets.

Recovery and resilience

Evaluates how well the polymer returns to its original shape after deformation and how quickly it does so.

Peel strength

Measuring the force required to peel a polymer layer from another surface, useful for adhesive applications.

Impact resistance

Evaluating the polymer's resistance to sudden forces or shocks.

Yield strain/strength

The point at which the material undergoes permanent deformation or begins to flow under applied stress.

Puncture/penetration resistance

Evaluates the force required to pierce through the polymer, which is essential for applications like packaging or protective gear.

Tensile strength

The maximum amount of tensile stress that a material can withstand without breaking. This property determines how well a polymer can resist stretching forces.

Adhesive strength

For polymers used as adhesives, this tests the force required to separate bonded materials.

Shear strength

The maximum force a polymer can take before sliding layers start to slide against each other.

Creep and stress relaxation

Creep measures the deformation of the polymer over time under a constant stress, while stress relaxation assesses the decrease in stress under constant strain.

Film durability

Testing the strength and resilience of thin polymer films or coatings.

Friction and slip

Measures how the surface of the polymer interacts with other surfaces. This is particularly relevant for polymers used in moving parts or where grip is essential.

Viscoelastic properties

For softer polymers or gels, understanding their combined viscous and elastic behaviours under various conditions.

Elastic modulus/Young’s modulus

Quantifies the stiffness or rigidity of the material and represents its ability to resist deformation under applied stress.

Texture Analysers, coupled with the appropriate attachments and probes, provide valuable insights into the mechanical performance of polymers. Such data is crucial for research and development, quality control, and application-specific optimisation of polymer materials.

Polymer raw materials also come in powder form. These can be measured using powder measurements such as Powder Flow Analysis, Unconfined Yield Stress and Powder Vertical Shear.

Typical graphs indicating relevant mechanical property parameters

Graph showing measurement of polymer gel capsule compression failure using a Cylinder Probe
Measurement of polymer gel capsule compression failure using a Cylinder Probe
Graph showing comparison of typical polymer deformation behaviours
Comparison of typical polymer deformation behaviours

Typical product test and graph

Case studies

Whether its providing the solution for Argenta Innovation to measure the polymer peak strength for their intraruminal device, allowing the Population Council to characterise their polymer for developing a birth control device or offering a method for Akina Inc to measure the tensile strength of their environmentally degradable alkyl polyester patent, a materials testing instrument is adaptable and flexible in its application to measure the bespoke mechanical properties of your product and then enable its quality to be controlled in your manufacturing to guarantee consistency and customer satisfaction.

With deep expertise in physical property measurement of materials, we’re well equipped to support innovation in this sector – just ask our customers.

Probes and attachments for measuring the mechanical properties of polymers

A wide range of probes and attachments can be integrated with our instruments, allowing testing to be precisely adapted to the material or product under evaluation. Applications include compression tests to compare polymer compressive strength, bending tests to assess flexural stiffness or tensile tests to measure and control tensile resilience or material elongation properties. 

Over the years, we have collaborated with leading scientists and organisations across diverse industries to design and refine attachments that meet highly specific testing requirements. When a suitable solution does not already exist, we develop one – expanding our portfolio of Community Registered Designs and reinforcing our commitment to innovation in solving complex testing challenges. The Mini Stickiness System is just one example of this.

The examples provided illustrate a selection of specialised attachments and commonly performed measurements in this application area. This list is not exhaustive; a wide range of additional options are available for the testing of food packaging. All instruments in the Texture Analyser range can be used to perform the tests described.

Compression test

Example standards: ASTM D695, ISO 604.

Tensile Test

Example standards: ASTM D638, ISO 527, ASTM D882, ASTM D412.

Flexure/Three point bend test

Example standards: ASTM D790, ISO 178.

Biaxial tension/puncture using Film Support Rig

HDP/FSR

Indentation test using Shore/Brinell/Vickers Hardness Probes

Example standard: ISO 7619-1.

Mini Stickiness System

Viscous polymer stickiness measurement.

Coefficient of friction test

A/FR

Test methods

As with any sample type, there are industry specifications that must be complied with. Many manufacturers, particularly those in consumer, automotive, medical and aerospace industries, choose to test their samples according to standard methods. Exponent Connect software includes a comprehensive range of test methods for polymers (including ASTM and ISO Standards), all instantly accessible at the click of a button. We streamline your texture testing process, ensuring faster access to methods and ready-to-use analysis files for your product properties.

Using the Texture Analyser for new polymer material and product ideas

Polymers, being versatile and adaptable materials, have seen continuous evolution in response to industrial demands, environmental concerns, and technological advances. Here are some of the newer ingredient and product ideas in the polymer sector:

Bio-based polymers

Derived from renewable resources like plants or biowaste, these polymers aim to be more sustainable than traditional petroleum-based ones. Examples include Polylactic Acid (PLA) and Polyhydroxyalkanoates (PHA).

High-performance polymers

These are developed for specific, often demanding applications, such as aerospace or medical implants. Examples include Polyetheretherketone (PEEK) and Polysulfone (PSU).

Smart polymers

These change their properties in response to external stimuli such as temperature, pH, or light. This makes them valuable in various applications like drug delivery and self-healing materials.

Recycled polymers

Given the environmental concerns, there's a push towards creating high-quality polymers from recycled materials, ensuring a circular economy.

Multi-block copolymers

These consist of different polymer chains linked together, aiming to combine the best properties of each polymer type.

Self-healing polymers

Materials that can repair themselves after damage.

Eco-friendly packaging

Using biodegradable or bio-based polymers for sustainable packaging solutions.

Polymer blends and alloys

Combining different polymers to achieve desirable properties.

Flexible and wearable electronics

Conductive polymers used in bendable displays, sensors, and wearable devices.

Biodegradable polymers

These are designed to break down in the environment over time, reducing long-term waste. Examples include Polybutylene Adipate Terephthalate (PBAT) and some grades of Polybutylene Succinate (PBS).

Conductive polymers

Polymers that can conduct electricity, useful in flexible electronics, sensors, and more. Examples include polyaniline and poly(3,4-ethylenedioxythiophene) or PEDOT.

Nanocomposite polymers

Polymers incorporated with nanoparticles to enhance their properties, such as mechanical strength, barrier properties, or conductivity.

Polymers for 3D printing

With the rise of 3D printing, specific resins or filament polymers are being developed that are optimised for various printing techniques, like Fused Deposition Modelling (FDM) or Stereolithography (SLA).

Shape memory polymers

Polymers that return to their original shape after being deformed when subjected to an external stimulus like heat.

Water-soluble polymers

Examples include polyvinyl alcohol (PVA) and are often used in medical or environmental applications.

Advanced textiles

Polymers that provide special functionalities to textiles like water repellency, UV protection, or antimicrobial properties.

Green tires

Tires made using sustainable polymers or processes that reduce environmental impact.

The aforementioned ideas provide an overview of the cutting-edge developments and directions in which polymer science is heading. With global challenges such as environmental concerns and the need for advanced functionalities, polymers will continue to play a crucial role in many industries.

Recent research

Here is some recent interesting research in polymer product development using the Texture Analyser:

  • Impact of structural relaxation on mechanical properties of amorphous polymers
  • Characterization of hydrophilic polymers as a syringe extrusion 3D printing material for orodispersible film
  • 4D printing of biodegradable elastomers with tailorable thermal response at physiological temperature
  • Robust polymer foams from 2-hydroxyethyl cellulose: Fabrication, stability, and chemical functionalization
  • Rheological and textural properties of hydrogels, containing sulfur as a model drug, made using different polymers types
  • Investigation on hot melt extrusion and prediction on 3D printability of pharmaceutical grade polymers
  • Effect of starch and hydroxypropyl methylcellulose polymers on the properties of orally disintegrating films

Contents

  • Why measure the mechanical properties of polymers?
  • How a Texture Analyser can be applied to polymer mechanical property measurement?
  • Typical measurements
  • Typical graphs indicating relevant mechanical property parameters
  • Typical product test and graph
  • Case studies
  • Probes and attachments for measuring the mechanical properties of polymers
  • Test methods
  • Using the Texture Analyser for new polymer material and product ideas
  • Recent research

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